What exact color does ozone gas have?












12












$begingroup$


This answer to a now closed question says that ozone gas has a "slight blue" color. But there are lots of blue colors: sky blue, ultramarine, phthalo blue, many others — what is closer to the color of ozone?



This page shows photos of ozone solutions in water, like the one below, but this may not be representative of the color of the gas.



pure water vs ozone>100ppm (source)



So, what exactly color does ozone gas have? Is it a single hue, or does it change depending on concentration/amount of ozone?










share|improve this question











$endgroup$












  • $begingroup$
    For some reasons, the ozonated water bottle looks odd. I searched Google and elsewhere nobody ever mentions that ozonated water has a bluish tinge except the link shared by the author. Are there any other references which mention that ozonated water is blue?
    $endgroup$
    – M. Farooq
    Mar 23 at 12:50










  • $begingroup$
    @M.Farooq I think you've not seen this anywhere else because the water in the photos has quite high concentration of ozone. As is told in the blog entry linked in the OP, "The blue color in the water starts to become visually evident above 50 ppm.".
    $endgroup$
    – Ruslan
    Mar 23 at 13:06










  • $begingroup$
    I was asking out of curiosity as to why nobody mentions the color of ozonated water anywhere. Ozonation is a very old technology but how come every one is silent on the color of ozone dissolved in water. The key question is if we have 50 ppm of O3 gas in air in a glass tube, will be see blue color?
    $endgroup$
    – M. Farooq
    Mar 23 at 13:56
















12












$begingroup$


This answer to a now closed question says that ozone gas has a "slight blue" color. But there are lots of blue colors: sky blue, ultramarine, phthalo blue, many others — what is closer to the color of ozone?



This page shows photos of ozone solutions in water, like the one below, but this may not be representative of the color of the gas.



pure water vs ozone>100ppm (source)



So, what exactly color does ozone gas have? Is it a single hue, or does it change depending on concentration/amount of ozone?










share|improve this question











$endgroup$












  • $begingroup$
    For some reasons, the ozonated water bottle looks odd. I searched Google and elsewhere nobody ever mentions that ozonated water has a bluish tinge except the link shared by the author. Are there any other references which mention that ozonated water is blue?
    $endgroup$
    – M. Farooq
    Mar 23 at 12:50










  • $begingroup$
    @M.Farooq I think you've not seen this anywhere else because the water in the photos has quite high concentration of ozone. As is told in the blog entry linked in the OP, "The blue color in the water starts to become visually evident above 50 ppm.".
    $endgroup$
    – Ruslan
    Mar 23 at 13:06










  • $begingroup$
    I was asking out of curiosity as to why nobody mentions the color of ozonated water anywhere. Ozonation is a very old technology but how come every one is silent on the color of ozone dissolved in water. The key question is if we have 50 ppm of O3 gas in air in a glass tube, will be see blue color?
    $endgroup$
    – M. Farooq
    Mar 23 at 13:56














12












12








12


2



$begingroup$


This answer to a now closed question says that ozone gas has a "slight blue" color. But there are lots of blue colors: sky blue, ultramarine, phthalo blue, many others — what is closer to the color of ozone?



This page shows photos of ozone solutions in water, like the one below, but this may not be representative of the color of the gas.



pure water vs ozone>100ppm (source)



So, what exactly color does ozone gas have? Is it a single hue, or does it change depending on concentration/amount of ozone?










share|improve this question











$endgroup$




This answer to a now closed question says that ozone gas has a "slight blue" color. But there are lots of blue colors: sky blue, ultramarine, phthalo blue, many others — what is closer to the color of ozone?



This page shows photos of ozone solutions in water, like the one below, but this may not be representative of the color of the gas.



pure water vs ozone>100ppm (source)



So, what exactly color does ozone gas have? Is it a single hue, or does it change depending on concentration/amount of ozone?







inorganic-chemistry color






share|improve this question















share|improve this question













share|improve this question




share|improve this question








edited Mar 22 at 23:00









MackTuesday

22519




22519










asked Mar 22 at 19:28









RuslanRuslan

539215




539215












  • $begingroup$
    For some reasons, the ozonated water bottle looks odd. I searched Google and elsewhere nobody ever mentions that ozonated water has a bluish tinge except the link shared by the author. Are there any other references which mention that ozonated water is blue?
    $endgroup$
    – M. Farooq
    Mar 23 at 12:50










  • $begingroup$
    @M.Farooq I think you've not seen this anywhere else because the water in the photos has quite high concentration of ozone. As is told in the blog entry linked in the OP, "The blue color in the water starts to become visually evident above 50 ppm.".
    $endgroup$
    – Ruslan
    Mar 23 at 13:06










  • $begingroup$
    I was asking out of curiosity as to why nobody mentions the color of ozonated water anywhere. Ozonation is a very old technology but how come every one is silent on the color of ozone dissolved in water. The key question is if we have 50 ppm of O3 gas in air in a glass tube, will be see blue color?
    $endgroup$
    – M. Farooq
    Mar 23 at 13:56


















  • $begingroup$
    For some reasons, the ozonated water bottle looks odd. I searched Google and elsewhere nobody ever mentions that ozonated water has a bluish tinge except the link shared by the author. Are there any other references which mention that ozonated water is blue?
    $endgroup$
    – M. Farooq
    Mar 23 at 12:50










  • $begingroup$
    @M.Farooq I think you've not seen this anywhere else because the water in the photos has quite high concentration of ozone. As is told in the blog entry linked in the OP, "The blue color in the water starts to become visually evident above 50 ppm.".
    $endgroup$
    – Ruslan
    Mar 23 at 13:06










  • $begingroup$
    I was asking out of curiosity as to why nobody mentions the color of ozonated water anywhere. Ozonation is a very old technology but how come every one is silent on the color of ozone dissolved in water. The key question is if we have 50 ppm of O3 gas in air in a glass tube, will be see blue color?
    $endgroup$
    – M. Farooq
    Mar 23 at 13:56
















$begingroup$
For some reasons, the ozonated water bottle looks odd. I searched Google and elsewhere nobody ever mentions that ozonated water has a bluish tinge except the link shared by the author. Are there any other references which mention that ozonated water is blue?
$endgroup$
– M. Farooq
Mar 23 at 12:50




$begingroup$
For some reasons, the ozonated water bottle looks odd. I searched Google and elsewhere nobody ever mentions that ozonated water has a bluish tinge except the link shared by the author. Are there any other references which mention that ozonated water is blue?
$endgroup$
– M. Farooq
Mar 23 at 12:50












$begingroup$
@M.Farooq I think you've not seen this anywhere else because the water in the photos has quite high concentration of ozone. As is told in the blog entry linked in the OP, "The blue color in the water starts to become visually evident above 50 ppm.".
$endgroup$
– Ruslan
Mar 23 at 13:06




$begingroup$
@M.Farooq I think you've not seen this anywhere else because the water in the photos has quite high concentration of ozone. As is told in the blog entry linked in the OP, "The blue color in the water starts to become visually evident above 50 ppm.".
$endgroup$
– Ruslan
Mar 23 at 13:06












$begingroup$
I was asking out of curiosity as to why nobody mentions the color of ozonated water anywhere. Ozonation is a very old technology but how come every one is silent on the color of ozone dissolved in water. The key question is if we have 50 ppm of O3 gas in air in a glass tube, will be see blue color?
$endgroup$
– M. Farooq
Mar 23 at 13:56




$begingroup$
I was asking out of curiosity as to why nobody mentions the color of ozonated water anywhere. Ozonation is a very old technology but how come every one is silent on the color of ozone dissolved in water. The key question is if we have 50 ppm of O3 gas in air in a glass tube, will be see blue color?
$endgroup$
– M. Farooq
Mar 23 at 13:56










1 Answer
1






active

oldest

votes


















19












$begingroup$

Due to Chappuis absorption, ozone does have a bluish color. To determine exactly what kind of blue it is, let's first look at the spectrum of absorption in the Chappuis band. The following plot was done using these data for 293K.



Chappuis band spectrum



This is spectral cross-section of absorption. To determine color from this spectrum, we need to choose some parameters:




  1. Number density of ozone molecules,

  2. Thickness of ozone layer we're trying to visualize,

  3. Illuminant.


If we denote spectral radiance of our illuminant as $L(lambda)$, thickness of ozone layer as $d$, ozone molecule number density as $rho$, and absorption cross-section as $sigma(lambda)$, then we'll get the following expression for spectral radiance transmitted through the layer:



$$L_T(lambda)=L(lambda)expbig(-sigma(lambda)rho dbig).$$



The most sensible illuminant to choose for showing color of a material on the web is the CIE illuminant D65, whose color is the white point of the sRGB color space. Its spectrum can be found e.g. here.



We can find the color in XYZ space using CIE 1931 color matching functions (can be found e.g. here). The expression is



$$c_X=int_{300}^{830}L_T(lambda)bar x(lambda),mathrm dlambda,$$



and similarly for $Y$ and $Z$ coordinates. Then these can be transformed to sRGB using linear transformation matrix $mathrm{XYZ}tomathrm{sRGB}$ given e.g. here and gamma-correcting to $gamma=1/2.2$ to yield final sRGB values.



Then, for ozone molecule number density $rho=10^{25} frac{mathrm{molecule}}{mathrm{m}^3}$ we'll get the following colors for different layer thicknesses:



colors of ozone at different layer thickness values



For comparison, typical ozone column in the atmospheric ozone layer is about 300 Dobson units, which is equivalent to $2.687times10^{20}frac{mathrm{molecule}}{mathrm m^2}$; with our $rho$ chosen above this corresponds to $d=8,mathrm{mm}$. So for daylight, ozone column has negligible effect on the sky color (unlike the evening — see the history of Chappuis absorption!).



As can be seen in the above plot, hue does change with increasing layer thickness. If we normalize the RGB values to see the hues of the thick layers (this would correspond to increasing illuminant power to compensate for absorption), we'll get the following hues:



hues of ozone at different layer thickness values



Note that the violet hues in the above plot aren't accurate: they can't be accurately represented on sRGB monitors, so the plot only approximates them. They should be more saturated. Here's how the chromaticity changes from the white point to the most violet with increasing layer thickness (dashed triangle denotes the sRGB gamut):



chromaticity xy coordinates of ozone layers of different thickness






share|improve this answer











$endgroup$









  • 1




    $begingroup$
    Nice answer, but why did you ask the question? ;-)
    $endgroup$
    – Karl
    Mar 22 at 21:02






  • 4




    $begingroup$
    @Karl Own Q-A duets are perfectly fine :)
    $endgroup$
    – andselisk
    Mar 22 at 21:15






  • 9




    $begingroup$
    @Karl because the other question where I could have posted the answer is closed, and unlikely to be reopened given how long ago it happened. But since I think the question is still relevant (in the form "what color" instead of "does it have a color"), not easily (if at all) answered by googling, and interesting, I made this Q&A.
    $endgroup$
    – Ruslan
    Mar 22 at 21:21








  • 3




    $begingroup$
    I just wanted to say that I've always loved sunsets, but until now I would never have guessed ozone was part of the reason; those deep blue-purples, contrasting with the orange-reds from Rayleigh scattering. You learn something new every day! Thanks so much for this contribution!
    $endgroup$
    – Nicolau Saker Neto
    Mar 22 at 23:12






  • 1




    $begingroup$
    @TLW I don't think there's any relation. sRGB was based on capabilities of CRTs of its time. Colors in CRTs are generated by luminescence, not by absorption, and blue phosphor is usually ZnS:Ag (P11 phosphor), which has no relation to ozone.
    $endgroup$
    – Ruslan
    Mar 23 at 6:43














Your Answer





StackExchange.ifUsing("editor", function () {
return StackExchange.using("mathjaxEditing", function () {
StackExchange.MarkdownEditor.creationCallbacks.add(function (editor, postfix) {
StackExchange.mathjaxEditing.prepareWmdForMathJax(editor, postfix, [["$", "$"], ["\\(","\\)"]]);
});
});
}, "mathjax-editing");

StackExchange.ready(function() {
var channelOptions = {
tags: "".split(" "),
id: "431"
};
initTagRenderer("".split(" "), "".split(" "), channelOptions);

StackExchange.using("externalEditor", function() {
// Have to fire editor after snippets, if snippets enabled
if (StackExchange.settings.snippets.snippetsEnabled) {
StackExchange.using("snippets", function() {
createEditor();
});
}
else {
createEditor();
}
});

function createEditor() {
StackExchange.prepareEditor({
heartbeatType: 'answer',
autoActivateHeartbeat: false,
convertImagesToLinks: false,
noModals: true,
showLowRepImageUploadWarning: true,
reputationToPostImages: null,
bindNavPrevention: true,
postfix: "",
imageUploader: {
brandingHtml: "Powered by u003ca class="icon-imgur-white" href="https://imgur.com/"u003eu003c/au003e",
contentPolicyHtml: "User contributions licensed under u003ca href="https://creativecommons.org/licenses/by-sa/3.0/"u003ecc by-sa 3.0 with attribution requiredu003c/au003e u003ca href="https://stackoverflow.com/legal/content-policy"u003e(content policy)u003c/au003e",
allowUrls: true
},
onDemand: true,
discardSelector: ".discard-answer"
,immediatelyShowMarkdownHelp:true
});


}
});














draft saved

draft discarded


















StackExchange.ready(
function () {
StackExchange.openid.initPostLogin('.new-post-login', 'https%3a%2f%2fchemistry.stackexchange.com%2fquestions%2f111389%2fwhat-exact-color-does-ozone-gas-have%23new-answer', 'question_page');
}
);

Post as a guest















Required, but never shown

























1 Answer
1






active

oldest

votes








1 Answer
1






active

oldest

votes









active

oldest

votes






active

oldest

votes









19












$begingroup$

Due to Chappuis absorption, ozone does have a bluish color. To determine exactly what kind of blue it is, let's first look at the spectrum of absorption in the Chappuis band. The following plot was done using these data for 293K.



Chappuis band spectrum



This is spectral cross-section of absorption. To determine color from this spectrum, we need to choose some parameters:




  1. Number density of ozone molecules,

  2. Thickness of ozone layer we're trying to visualize,

  3. Illuminant.


If we denote spectral radiance of our illuminant as $L(lambda)$, thickness of ozone layer as $d$, ozone molecule number density as $rho$, and absorption cross-section as $sigma(lambda)$, then we'll get the following expression for spectral radiance transmitted through the layer:



$$L_T(lambda)=L(lambda)expbig(-sigma(lambda)rho dbig).$$



The most sensible illuminant to choose for showing color of a material on the web is the CIE illuminant D65, whose color is the white point of the sRGB color space. Its spectrum can be found e.g. here.



We can find the color in XYZ space using CIE 1931 color matching functions (can be found e.g. here). The expression is



$$c_X=int_{300}^{830}L_T(lambda)bar x(lambda),mathrm dlambda,$$



and similarly for $Y$ and $Z$ coordinates. Then these can be transformed to sRGB using linear transformation matrix $mathrm{XYZ}tomathrm{sRGB}$ given e.g. here and gamma-correcting to $gamma=1/2.2$ to yield final sRGB values.



Then, for ozone molecule number density $rho=10^{25} frac{mathrm{molecule}}{mathrm{m}^3}$ we'll get the following colors for different layer thicknesses:



colors of ozone at different layer thickness values



For comparison, typical ozone column in the atmospheric ozone layer is about 300 Dobson units, which is equivalent to $2.687times10^{20}frac{mathrm{molecule}}{mathrm m^2}$; with our $rho$ chosen above this corresponds to $d=8,mathrm{mm}$. So for daylight, ozone column has negligible effect on the sky color (unlike the evening — see the history of Chappuis absorption!).



As can be seen in the above plot, hue does change with increasing layer thickness. If we normalize the RGB values to see the hues of the thick layers (this would correspond to increasing illuminant power to compensate for absorption), we'll get the following hues:



hues of ozone at different layer thickness values



Note that the violet hues in the above plot aren't accurate: they can't be accurately represented on sRGB monitors, so the plot only approximates them. They should be more saturated. Here's how the chromaticity changes from the white point to the most violet with increasing layer thickness (dashed triangle denotes the sRGB gamut):



chromaticity xy coordinates of ozone layers of different thickness






share|improve this answer











$endgroup$









  • 1




    $begingroup$
    Nice answer, but why did you ask the question? ;-)
    $endgroup$
    – Karl
    Mar 22 at 21:02






  • 4




    $begingroup$
    @Karl Own Q-A duets are perfectly fine :)
    $endgroup$
    – andselisk
    Mar 22 at 21:15






  • 9




    $begingroup$
    @Karl because the other question where I could have posted the answer is closed, and unlikely to be reopened given how long ago it happened. But since I think the question is still relevant (in the form "what color" instead of "does it have a color"), not easily (if at all) answered by googling, and interesting, I made this Q&A.
    $endgroup$
    – Ruslan
    Mar 22 at 21:21








  • 3




    $begingroup$
    I just wanted to say that I've always loved sunsets, but until now I would never have guessed ozone was part of the reason; those deep blue-purples, contrasting with the orange-reds from Rayleigh scattering. You learn something new every day! Thanks so much for this contribution!
    $endgroup$
    – Nicolau Saker Neto
    Mar 22 at 23:12






  • 1




    $begingroup$
    @TLW I don't think there's any relation. sRGB was based on capabilities of CRTs of its time. Colors in CRTs are generated by luminescence, not by absorption, and blue phosphor is usually ZnS:Ag (P11 phosphor), which has no relation to ozone.
    $endgroup$
    – Ruslan
    Mar 23 at 6:43


















19












$begingroup$

Due to Chappuis absorption, ozone does have a bluish color. To determine exactly what kind of blue it is, let's first look at the spectrum of absorption in the Chappuis band. The following plot was done using these data for 293K.



Chappuis band spectrum



This is spectral cross-section of absorption. To determine color from this spectrum, we need to choose some parameters:




  1. Number density of ozone molecules,

  2. Thickness of ozone layer we're trying to visualize,

  3. Illuminant.


If we denote spectral radiance of our illuminant as $L(lambda)$, thickness of ozone layer as $d$, ozone molecule number density as $rho$, and absorption cross-section as $sigma(lambda)$, then we'll get the following expression for spectral radiance transmitted through the layer:



$$L_T(lambda)=L(lambda)expbig(-sigma(lambda)rho dbig).$$



The most sensible illuminant to choose for showing color of a material on the web is the CIE illuminant D65, whose color is the white point of the sRGB color space. Its spectrum can be found e.g. here.



We can find the color in XYZ space using CIE 1931 color matching functions (can be found e.g. here). The expression is



$$c_X=int_{300}^{830}L_T(lambda)bar x(lambda),mathrm dlambda,$$



and similarly for $Y$ and $Z$ coordinates. Then these can be transformed to sRGB using linear transformation matrix $mathrm{XYZ}tomathrm{sRGB}$ given e.g. here and gamma-correcting to $gamma=1/2.2$ to yield final sRGB values.



Then, for ozone molecule number density $rho=10^{25} frac{mathrm{molecule}}{mathrm{m}^3}$ we'll get the following colors for different layer thicknesses:



colors of ozone at different layer thickness values



For comparison, typical ozone column in the atmospheric ozone layer is about 300 Dobson units, which is equivalent to $2.687times10^{20}frac{mathrm{molecule}}{mathrm m^2}$; with our $rho$ chosen above this corresponds to $d=8,mathrm{mm}$. So for daylight, ozone column has negligible effect on the sky color (unlike the evening — see the history of Chappuis absorption!).



As can be seen in the above plot, hue does change with increasing layer thickness. If we normalize the RGB values to see the hues of the thick layers (this would correspond to increasing illuminant power to compensate for absorption), we'll get the following hues:



hues of ozone at different layer thickness values



Note that the violet hues in the above plot aren't accurate: they can't be accurately represented on sRGB monitors, so the plot only approximates them. They should be more saturated. Here's how the chromaticity changes from the white point to the most violet with increasing layer thickness (dashed triangle denotes the sRGB gamut):



chromaticity xy coordinates of ozone layers of different thickness






share|improve this answer











$endgroup$









  • 1




    $begingroup$
    Nice answer, but why did you ask the question? ;-)
    $endgroup$
    – Karl
    Mar 22 at 21:02






  • 4




    $begingroup$
    @Karl Own Q-A duets are perfectly fine :)
    $endgroup$
    – andselisk
    Mar 22 at 21:15






  • 9




    $begingroup$
    @Karl because the other question where I could have posted the answer is closed, and unlikely to be reopened given how long ago it happened. But since I think the question is still relevant (in the form "what color" instead of "does it have a color"), not easily (if at all) answered by googling, and interesting, I made this Q&A.
    $endgroup$
    – Ruslan
    Mar 22 at 21:21








  • 3




    $begingroup$
    I just wanted to say that I've always loved sunsets, but until now I would never have guessed ozone was part of the reason; those deep blue-purples, contrasting with the orange-reds from Rayleigh scattering. You learn something new every day! Thanks so much for this contribution!
    $endgroup$
    – Nicolau Saker Neto
    Mar 22 at 23:12






  • 1




    $begingroup$
    @TLW I don't think there's any relation. sRGB was based on capabilities of CRTs of its time. Colors in CRTs are generated by luminescence, not by absorption, and blue phosphor is usually ZnS:Ag (P11 phosphor), which has no relation to ozone.
    $endgroup$
    – Ruslan
    Mar 23 at 6:43
















19












19








19





$begingroup$

Due to Chappuis absorption, ozone does have a bluish color. To determine exactly what kind of blue it is, let's first look at the spectrum of absorption in the Chappuis band. The following plot was done using these data for 293K.



Chappuis band spectrum



This is spectral cross-section of absorption. To determine color from this spectrum, we need to choose some parameters:




  1. Number density of ozone molecules,

  2. Thickness of ozone layer we're trying to visualize,

  3. Illuminant.


If we denote spectral radiance of our illuminant as $L(lambda)$, thickness of ozone layer as $d$, ozone molecule number density as $rho$, and absorption cross-section as $sigma(lambda)$, then we'll get the following expression for spectral radiance transmitted through the layer:



$$L_T(lambda)=L(lambda)expbig(-sigma(lambda)rho dbig).$$



The most sensible illuminant to choose for showing color of a material on the web is the CIE illuminant D65, whose color is the white point of the sRGB color space. Its spectrum can be found e.g. here.



We can find the color in XYZ space using CIE 1931 color matching functions (can be found e.g. here). The expression is



$$c_X=int_{300}^{830}L_T(lambda)bar x(lambda),mathrm dlambda,$$



and similarly for $Y$ and $Z$ coordinates. Then these can be transformed to sRGB using linear transformation matrix $mathrm{XYZ}tomathrm{sRGB}$ given e.g. here and gamma-correcting to $gamma=1/2.2$ to yield final sRGB values.



Then, for ozone molecule number density $rho=10^{25} frac{mathrm{molecule}}{mathrm{m}^3}$ we'll get the following colors for different layer thicknesses:



colors of ozone at different layer thickness values



For comparison, typical ozone column in the atmospheric ozone layer is about 300 Dobson units, which is equivalent to $2.687times10^{20}frac{mathrm{molecule}}{mathrm m^2}$; with our $rho$ chosen above this corresponds to $d=8,mathrm{mm}$. So for daylight, ozone column has negligible effect on the sky color (unlike the evening — see the history of Chappuis absorption!).



As can be seen in the above plot, hue does change with increasing layer thickness. If we normalize the RGB values to see the hues of the thick layers (this would correspond to increasing illuminant power to compensate for absorption), we'll get the following hues:



hues of ozone at different layer thickness values



Note that the violet hues in the above plot aren't accurate: they can't be accurately represented on sRGB monitors, so the plot only approximates them. They should be more saturated. Here's how the chromaticity changes from the white point to the most violet with increasing layer thickness (dashed triangle denotes the sRGB gamut):



chromaticity xy coordinates of ozone layers of different thickness






share|improve this answer











$endgroup$



Due to Chappuis absorption, ozone does have a bluish color. To determine exactly what kind of blue it is, let's first look at the spectrum of absorption in the Chappuis band. The following plot was done using these data for 293K.



Chappuis band spectrum



This is spectral cross-section of absorption. To determine color from this spectrum, we need to choose some parameters:




  1. Number density of ozone molecules,

  2. Thickness of ozone layer we're trying to visualize,

  3. Illuminant.


If we denote spectral radiance of our illuminant as $L(lambda)$, thickness of ozone layer as $d$, ozone molecule number density as $rho$, and absorption cross-section as $sigma(lambda)$, then we'll get the following expression for spectral radiance transmitted through the layer:



$$L_T(lambda)=L(lambda)expbig(-sigma(lambda)rho dbig).$$



The most sensible illuminant to choose for showing color of a material on the web is the CIE illuminant D65, whose color is the white point of the sRGB color space. Its spectrum can be found e.g. here.



We can find the color in XYZ space using CIE 1931 color matching functions (can be found e.g. here). The expression is



$$c_X=int_{300}^{830}L_T(lambda)bar x(lambda),mathrm dlambda,$$



and similarly for $Y$ and $Z$ coordinates. Then these can be transformed to sRGB using linear transformation matrix $mathrm{XYZ}tomathrm{sRGB}$ given e.g. here and gamma-correcting to $gamma=1/2.2$ to yield final sRGB values.



Then, for ozone molecule number density $rho=10^{25} frac{mathrm{molecule}}{mathrm{m}^3}$ we'll get the following colors for different layer thicknesses:



colors of ozone at different layer thickness values



For comparison, typical ozone column in the atmospheric ozone layer is about 300 Dobson units, which is equivalent to $2.687times10^{20}frac{mathrm{molecule}}{mathrm m^2}$; with our $rho$ chosen above this corresponds to $d=8,mathrm{mm}$. So for daylight, ozone column has negligible effect on the sky color (unlike the evening — see the history of Chappuis absorption!).



As can be seen in the above plot, hue does change with increasing layer thickness. If we normalize the RGB values to see the hues of the thick layers (this would correspond to increasing illuminant power to compensate for absorption), we'll get the following hues:



hues of ozone at different layer thickness values



Note that the violet hues in the above plot aren't accurate: they can't be accurately represented on sRGB monitors, so the plot only approximates them. They should be more saturated. Here's how the chromaticity changes from the white point to the most violet with increasing layer thickness (dashed triangle denotes the sRGB gamut):



chromaticity xy coordinates of ozone layers of different thickness







share|improve this answer














share|improve this answer



share|improve this answer








edited Mar 22 at 21:29

























answered Mar 22 at 19:28









RuslanRuslan

539215




539215








  • 1




    $begingroup$
    Nice answer, but why did you ask the question? ;-)
    $endgroup$
    – Karl
    Mar 22 at 21:02






  • 4




    $begingroup$
    @Karl Own Q-A duets are perfectly fine :)
    $endgroup$
    – andselisk
    Mar 22 at 21:15






  • 9




    $begingroup$
    @Karl because the other question where I could have posted the answer is closed, and unlikely to be reopened given how long ago it happened. But since I think the question is still relevant (in the form "what color" instead of "does it have a color"), not easily (if at all) answered by googling, and interesting, I made this Q&A.
    $endgroup$
    – Ruslan
    Mar 22 at 21:21








  • 3




    $begingroup$
    I just wanted to say that I've always loved sunsets, but until now I would never have guessed ozone was part of the reason; those deep blue-purples, contrasting with the orange-reds from Rayleigh scattering. You learn something new every day! Thanks so much for this contribution!
    $endgroup$
    – Nicolau Saker Neto
    Mar 22 at 23:12






  • 1




    $begingroup$
    @TLW I don't think there's any relation. sRGB was based on capabilities of CRTs of its time. Colors in CRTs are generated by luminescence, not by absorption, and blue phosphor is usually ZnS:Ag (P11 phosphor), which has no relation to ozone.
    $endgroup$
    – Ruslan
    Mar 23 at 6:43
















  • 1




    $begingroup$
    Nice answer, but why did you ask the question? ;-)
    $endgroup$
    – Karl
    Mar 22 at 21:02






  • 4




    $begingroup$
    @Karl Own Q-A duets are perfectly fine :)
    $endgroup$
    – andselisk
    Mar 22 at 21:15






  • 9




    $begingroup$
    @Karl because the other question where I could have posted the answer is closed, and unlikely to be reopened given how long ago it happened. But since I think the question is still relevant (in the form "what color" instead of "does it have a color"), not easily (if at all) answered by googling, and interesting, I made this Q&A.
    $endgroup$
    – Ruslan
    Mar 22 at 21:21








  • 3




    $begingroup$
    I just wanted to say that I've always loved sunsets, but until now I would never have guessed ozone was part of the reason; those deep blue-purples, contrasting with the orange-reds from Rayleigh scattering. You learn something new every day! Thanks so much for this contribution!
    $endgroup$
    – Nicolau Saker Neto
    Mar 22 at 23:12






  • 1




    $begingroup$
    @TLW I don't think there's any relation. sRGB was based on capabilities of CRTs of its time. Colors in CRTs are generated by luminescence, not by absorption, and blue phosphor is usually ZnS:Ag (P11 phosphor), which has no relation to ozone.
    $endgroup$
    – Ruslan
    Mar 23 at 6:43










1




1




$begingroup$
Nice answer, but why did you ask the question? ;-)
$endgroup$
– Karl
Mar 22 at 21:02




$begingroup$
Nice answer, but why did you ask the question? ;-)
$endgroup$
– Karl
Mar 22 at 21:02




4




4




$begingroup$
@Karl Own Q-A duets are perfectly fine :)
$endgroup$
– andselisk
Mar 22 at 21:15




$begingroup$
@Karl Own Q-A duets are perfectly fine :)
$endgroup$
– andselisk
Mar 22 at 21:15




9




9




$begingroup$
@Karl because the other question where I could have posted the answer is closed, and unlikely to be reopened given how long ago it happened. But since I think the question is still relevant (in the form "what color" instead of "does it have a color"), not easily (if at all) answered by googling, and interesting, I made this Q&A.
$endgroup$
– Ruslan
Mar 22 at 21:21






$begingroup$
@Karl because the other question where I could have posted the answer is closed, and unlikely to be reopened given how long ago it happened. But since I think the question is still relevant (in the form "what color" instead of "does it have a color"), not easily (if at all) answered by googling, and interesting, I made this Q&A.
$endgroup$
– Ruslan
Mar 22 at 21:21






3




3




$begingroup$
I just wanted to say that I've always loved sunsets, but until now I would never have guessed ozone was part of the reason; those deep blue-purples, contrasting with the orange-reds from Rayleigh scattering. You learn something new every day! Thanks so much for this contribution!
$endgroup$
– Nicolau Saker Neto
Mar 22 at 23:12




$begingroup$
I just wanted to say that I've always loved sunsets, but until now I would never have guessed ozone was part of the reason; those deep blue-purples, contrasting with the orange-reds from Rayleigh scattering. You learn something new every day! Thanks so much for this contribution!
$endgroup$
– Nicolau Saker Neto
Mar 22 at 23:12




1




1




$begingroup$
@TLW I don't think there's any relation. sRGB was based on capabilities of CRTs of its time. Colors in CRTs are generated by luminescence, not by absorption, and blue phosphor is usually ZnS:Ag (P11 phosphor), which has no relation to ozone.
$endgroup$
– Ruslan
Mar 23 at 6:43






$begingroup$
@TLW I don't think there's any relation. sRGB was based on capabilities of CRTs of its time. Colors in CRTs are generated by luminescence, not by absorption, and blue phosphor is usually ZnS:Ag (P11 phosphor), which has no relation to ozone.
$endgroup$
– Ruslan
Mar 23 at 6:43




















draft saved

draft discarded




















































Thanks for contributing an answer to Chemistry Stack Exchange!


  • Please be sure to answer the question. Provide details and share your research!

But avoid



  • Asking for help, clarification, or responding to other answers.

  • Making statements based on opinion; back them up with references or personal experience.


Use MathJax to format equations. MathJax reference.


To learn more, see our tips on writing great answers.




draft saved


draft discarded














StackExchange.ready(
function () {
StackExchange.openid.initPostLogin('.new-post-login', 'https%3a%2f%2fchemistry.stackexchange.com%2fquestions%2f111389%2fwhat-exact-color-does-ozone-gas-have%23new-answer', 'question_page');
}
);

Post as a guest















Required, but never shown





















































Required, but never shown














Required, but never shown












Required, but never shown







Required, but never shown

































Required, but never shown














Required, but never shown












Required, but never shown







Required, but never shown







Popular posts from this blog

If I really need a card on my start hand, how many mulligans make sense? [duplicate]

Alcedinidae

Can an atomic nucleus contain both particles and antiparticles? [duplicate]